
Episode 2
DESUBLIMATION
TECHNOLOGIES
Desublimation is the direct phase change of a substance from a gas to a solid, without an intermediate liquid state. This phenomenon naturally occurs in the formation of hoarfrost when water vapour from the ambient air freezes on contact with cold surfaces as ice crystals. Frost on the window in winter is a familiar example. Another is the frost formation in home freezers.
Desublimation is used in industrial processes as a thermodynamic method for separating a certain substance from a gas stream and is an alternative process to adsorption and absorption. The separation is achieved by cooling and heating in batch-operation. In the Desublimator the gas mixture comes into contact with cooled surfaces/ fins.
Here the substance of the gas mixture to be separated desublimates either around or below its triple point and adheres to the cold surface in crystalline form.
Kelvion has a long track record in desublimator technology for a wide range of substances in several applications. By extensive theoretical and practical work in recent years Kelvion has transformed this process also for the desublimation of CO₂. In the context of carbon capture, desublimation is an emerging and promising method used to separate carbon dioxide (CO₂) from gas streams without the need of additional media or chemicals.
All you need is a cold source, so this is a great solution for CO₂ capture applications.

PHYSICAL FUNDAMENTALS
Based on the log p/T diagram the process of desublimation and its difference to condensation gets clear.
CASE A
Phase change above triple point: CONDENSATION (rain-fall and dew-formation in nature)
CASE B
Phase change close above triple point: INDIRECT DESUBLIMATION (“freezing rain” or “dew” on cold surfaces in nature)
CASE C
Phase change below triple point: DIRECT DESUBLIMATION (snow-fall or crystallization in nature)
THREE STEPS TO REALISE DESUBLIMATION

KELVION INDUSTRIAL DESUBLIMATORS
1954
1995
2016
2021
2023





Invention and market introduction of Kelvion’s Desublimator specifically for the PA process with fintube technology (almost 1600 units supplied)
Invention and market introduction of Kelvion's Mini Desublimator for lower gas flows and low pressure applications
Invention and market introduction of Kelvion's Mini Desublimator for high pressure applications (patented technology)
Invention and market introduction of Kelvion's stainless-steel Desublimator with fintube technology
The first Kelvion desublimator for CO₂ capture installed in a pilot plant


FOCAL-POINT: CARBON CAPTURE
BY DESUBLIMATION
There are many ways to separate CO₂ in industrial processes.
In this paper we’ll focus on desublimation as an emerging and promising method to separate carbon dioxide from gas streams.
OUR SOLUTIONS FOR DESUBLIMATION TECHNOLOGIES

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Very clean process, as no chemicals or solvents are needed
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Separation efficiency for CO₂ -capture of almost 100%
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Highest purity of separated CO₂
at food grate level
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No moving parts means low wear, high operational reliability and virtually maintenance-free
Desublimator
Mini-Desublimator
