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Episode 2

DESUBLIMATION
TECHNOLOGIES

Desublimation is the direct phase change of a substance from a gas to a solid, without an intermediate liquid state. This phenomenon naturally occurs in the formation of hoarfrost when water vapour from the ambient air freezes on contact with cold surfaces as ice crystals. Frost on the window in winter is a familiar example. Another is the frost formation in home freezers.

Desublimation is used in industrial processes as a thermodynamic method for separating a certain substance from a gas stream and is an alternative process to adsorption and absorption. The separation is achieved by cooling and heating in batch-operation. In the Desublimator the gas mixture comes into contact with cooled surfaces/ fins.
Here the substance of the gas mixture to be separated desublimates either around or below its triple point and adheres to the cold surface in crystalline form.

 

Kelvion has a long track record in desublimator technology for a wide range of substances in several applications. By extensive theoretical and practical work in recent years Kelvion has transformed this process also for the desublimation of CO₂. In the context of carbon capture, desublimation is an emerging and promising method used to separate carbon dioxide (CO₂) from gas streams without the need of additional media or chemicals.

 

All you need is a cold source, so this is a great solution for CO₂ capture applications.​

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PHYSICAL FUNDAMENTALS

Based on the log p/T diagram the process of desublimation and its difference to condensation gets clear.

CASE A

Phase change above triple point: CONDENSATION (rain-fall and dew-formation in nature)

CASE B

Phase change close above triple point: INDIRECT DESUBLIMATION (“freezing rain” or “dew” on cold surfaces in nature)

CASE C

Phase change below triple point: DIRECT DESUBLIMATION (snow-fall or crystallization in nature)

THREE STEPS TO REALISE DESUBLIMATION

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KELVION INDUSTRIAL DESUBLIMATORS

1954

1995

2016

2021

2023

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Invention and market introduction of Kelvion’s Desublimator specifically for the PA process with fintube technology (almost 1600 units supplied)

Invention and market introduction of Kelvion's Mini Desublimator for lower gas flows and low pressure applications

Invention and market introduction of Kelvion's Mini Desublimator for high pressure applications (patented technology)

Invention and market introduction of Kelvion's stainless-steel Desublimator with fintube technology

The first Kelvion desublimator for CO capture installed in a pilot plant

DESUBLIMATOR CO2 PROCESS

Cooling Media

Heating Media

Decarbonized Gas OUT

Cooling Media

Heating Media

Process Gas 

MELTING

LOADING

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Liquid CO2

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FOCAL-POINT: CARBON CAPTURE
BY DESUBLIMATION

There are many ways to separate CO  in industrial processes.


In this paper we’ll focus on desublimation as an emerging and promising method to separate carbon dioxide from gas streams.

OUR SOLUTIONS FOR DESUBLIMATION TECHNOLOGIES

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  • Very clean process, as no chemicals or solvents are needed
     

  • Separation efficiency for CO -capture of almost 100%
     

  • Highest purity of separated CO 
    at food grate level 
     

  • No moving parts means low wear, high operational reliability and virtually maintenance-free 

Desublimator

Mini-Desublimator

FIND OUT MORE ABOUT
CAPTURE TOWER TECHNOLOGIES

COMING SOON

EPISODES

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ABSORPTION TECHNOLOGIES

DESUBLIMATION TECHNOLOGIES

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CAPTURE TOWER TECHNOLOGIES

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